Molecules With Square Antiprismatic Geometry
According to the VSEPR theory of molecular geometry in chemistry, which is based on the general principle of maximizing the distances between points, a square antiprism is the favoured geometry when eight pairs of electrons surround a central atom. One molecule with this geometry is the octafluoroxenate(VI) ion (XeF82-) in the salt nitrosonium octafluoroxenate(VI); however, the molecule is distorted away from the idealized square antiprism.
In addition, the element sulfur forms octatomic S8 molecules as its most stable allotrope. The S8 molecule has a structure based on the square antiprism, in which the eight atoms occupy the eight vertices of the antiprism, and the eight triangle-triangle edges of the antiprism correspond to single covalent bonds between sulfur atoms.
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