Publication History
The monster version of Scorpion first appeared in Journey into Mystery #82 (1962)
The Sam Scorpio version first appeared in Kid Colt, Outlaw #115 (March, 1964) and was a Wild West villain who fought Kid Colt.
The Jim Evans version of Scorpion first appeared in Rawhide Kid #57 (April 1967) and was a Wild West villain who fought Rawhide Kid.
Mac Gargan was created by Stan Lee and Steve Ditko. Gargan first appeared in The Amazing Spider-Man #19 (1964) and first appeared as the Scorpion in Amazing Spider-Man #20 (July, 1964). Years later, he became the third incarnation of Venom in Marvel Knights: Spider-Man #10 (2005) and the third Spider-Man in Dark Avengers #1 (2009). Mac Gargan appeared in the character's first own 4-issue limited series, Dark Reign: Sinister Spider-Man. The comic was released in June 2009 and was written by Brian Reed, with art by Chris Bachalo. Writer Dan Slott has stated that Mac Gargan will return as the original Scorpion, in an upcoming arc of The Amazing Spider-Man.
Carmilla Black first appeared in "Amazing Fantasy" vol 2. #7 (2005).
Read more about this topic: Scorpion (Marvel Comics)
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