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- Abbott Barnes Rice (1862–1926), businessman and Massachusetts state legislator
- Albert E. Rice (1845–1921), U.S. politician, Lt. Governor of Minnesota
- Alex Rice (born 1972), Canadian Fisrt Nations actress
- Alexander H. Rice, Jr. (1875–1956), U.S. geographer and explorer
- Alexander H. Rice (1818–1895), U.S. politician, Governor of Massachusetts
- Alice Hegan Rice (1870–1942), U.S. novelist
- Americus Vespucius Rice (1835–1904), U.S. Civil War general (Union) and U.S. Congressman
- Amy Rice (born 1966), U.S. Rhode Island state politician
- Angelena Rice (1924–1985), mother of U.S. public official Condoleezza Rice
- Anna Rice (born 1980) Canadian badminton player
- Anne Rice (born 1941), U.S. author of Gothic and religious themed novels
- Anneka Rice (born 1958), British television presenter
- Arthur Rice, 6th Baron Dynevor (1836–1911)
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