A reference electrode is an electrode which has a stable and well-known electrode potential. The high stability of the electrode potential is usually reached by employing a redox system with constant (buffered or saturated) concentrations of each participants of the redox reaction.
There are many ways reference electrodes are used. The simplest is when the reference electrode is used as a half cell to build an electrochemical cell. This allows the potential of the other half cell to be determined. An accurate and practical method to measure an electrode's potential in isolation (absolute electrode potential) has yet to be developed.
Read more about Reference Electrode: Aqueous Reference Electrodes, Nonaqueous Reference Electrodes, Pseudo-reference Electrodes
Famous quotes containing the word reference:
“In sum, all actions and habits are to be esteemed good or evil by their causes and usefulness in reference to the commonwealth, and not by their mediocrity, nor by their being commended. For several men praise several customs, and, contrarily, what one calls vice, another calls virtue, as their present affections lead them.”
—Thomas Hobbes (1579–1688)