Reductive Dechlorination - Electrochemical

Electrochemical

The electrochemical reduction of chlorinated chemicals such as chlorinated hydrocarbons and chlorofluorocarbons (CFCs) can be carried out by electrolysis of these pollutants in appropriate solvents, such as mixtures of water and alcohol. The cathode transfers electrons to the polluting molecule, which decomposes to produce the corresponding hydrocarbon (hydrogen atoms substitute the original chlorine atoms) and free chloride ions. For instance, the reductive dechlorination of CFCs is complete and produces several HFCs plus chloride.

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