Theory of Raman Optical Activity
The basic principle of Raman optical activity is that there is interference between light waves scattered by the polarizability and optical activity tensors of a chiral molecule, which leads to a difference between the intensities of the right- and left-handed circularly polarised scattered beams. The spectrum of intensity differences recorded over a range of wavenumbers reveals information about chiral centres in the sample molecule.
Raman optical activity can be observed in a number of forms, depending on the polarization of the incident and the scattered light. For instance, in the scattered circular polarization (SCP) experiment, the incident light is linearly polarized and differences in circular polarization of the scattered light are measured. In the dual circular polarization (DCP), both the incident and the scattered light are circularly polarized, either in phase (DCPI ) or out of phase (DCPII ).
Read more about this topic: Raman Optical Activity
Famous quotes containing the words theory, optical and/or activity:
“There is in him, hidden deep-down, a great instinctive artist, and hence the makings of an aristocrat. In his muddled way, held back by the manacles of his race and time, and his steps made uncertain by a guiding theory which too often eludes his own comprehension, he yet manages to produce works of unquestionable beauty and authority, and to interpret life in a manner that is poignant and illuminating.”
—H.L. (Henry Lewis)
“The convent, which belongs to the West as it does to the East, to antiquity as it does to the present time, to Buddhism and Muhammadanism as it does to Christianity, is one of the optical devices whereby man gains a glimpse of infinity.”
—Victor Hugo (1802–1885)
“In communist society, where nobody has one exclusive sphere of activity but each can become accomplished in any branch he wishes, society regulates the general production and thus makes it possible for me to do one thing today and another tomorrow, to hunt in the morning, fish in the afternoon, rear cattle in the evening, criticize after dinner, just as I have a mind, without ever becoming hunter, fisherman, shepherd or critic.”
—Karl Marx (1818–1883)