Other Characterizations
An alternative characterization of PSPACE is the set of problems decidable by an alternating Turing machine in polynomial time, sometimes called APTIME or just AP.
A logical characterization of PSPACE from descriptive complexity theory is that it is the set of problems expressible in second-order logic with the addition of a transitive closure operator. A full transitive closure is not needed; a commutative transitive closure and even weaker forms suffice. It is the addition of this operator that (possibly) distinguishes PSPACE from PH.
A major result of complexity theory is that PSPACE can be characterized as all the languages recognizable by a particular interactive proof system, the one defining the class IP. In this system, there is an all-powerful prover trying to convince a randomized polynomial-time verifier that a string is in the language. It should be able to convince the verifier with high probability if the string is in the language, but should not be able to convince it except with low probability if the string is not in the language.
PSPACE can be characterized as the quantum complexity class QIP.
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