Photosensitization
Photosensitization is a process of transferring the energy of absorbed light. After absorption, the energy is transferred to the (chosen) reactants. This is part of the work of photochemistry in general. In particular this process is commonly employed where reactions require light sources of certain wavelengths that are not readily available.
For example, mercury absorbs radiation at 1849 and 2537 angstroms, and the source is often high-intensity mercury lamps. It is a commonly used sensitizer. When mercury vapor is mixed with ethylene, and the compound is irradiated with a mercury lamp, this results in the photodecomposition of ethylene to acetylene. This occurs on absorption of light to yield excited state mercury atoms, which are able to transfer this energy to the ethylene molecules, and are in turn deactivated to their initial energy state.
Cadmium; some of the noble gases, for example xenon; zinc; benzophenone; and a large number of organic dyes, are also used as sensitizers.
Photosensitisers are a key component of photodynamic therapy used to treat cancers.
Read more about this topic: Photosensitizing Agents