Organotins - Reactions of Organotin Compounds

Reactions of Organotin Compounds

Important reactions involving organotin compounds are the Stille reaction (coupling reaction with sp2-hybridized organic halides catalyzed by palladium):

and organostannane additions (nucleophilic addition of an allyl-, allenyl-, or propargylstannanes to an aldehydes and imines). Organotin compounds are also used extensively in radical chemistry (e.g. radical cyclizations, Barton–McCombie deoxygenation, Barton decarboxylation, etc.).

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