Significant Works
Semyonov's outstanding work on the mechanism of chemical transformation includes an exhaustive analysis of the application of the chain theory to varied reactions (1934–1954) and, more significantly, to combustion processes. He proposed a theory of degenerate branching, which led to a better understanding of the phenomena associated with the induction periods of oxidation processes.
Semyonov wrote two important books outlining his work. Chemical Kinetics and Chain Reactions was published in 1934 with an English edition in 1935. It was the first book in the U.S.S.R. to develop a detailed theory of unbranched and branched chain reactions in chemistry. Some Problems of Chemical Kinetics and Reactivity, first published in 1954, was revised in 1958; there are also English, American, German, and Chinese editions. In 1956, he was awarded the Nobel Prize in Chemistry (together with Sir Cyril Norman Hinshelwood) for this work.
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