Nernst Equation - Relation To Equilibrium

Relation To Equilibrium

At equilibrium, E = 0 and Q = K. Therefore

\begin{align} 0 &= E^o - \frac{RT}{nF} \ln K\\ \ln K &= \frac{nFE^o}{RT} \end{align}

Or at standard temperature,

We have thus related the standard electrode potential and the equilibrium constant of a redox reaction.

Read more about this topic:  Nernst Equation

Famous quotes containing the words relation to, relation and/or equilibrium:

    “It would be disingenuous, however, not to point out that some things are considered as morally certain, that is, as having sufficient certainty for application to ordinary life, even though they may be uncertain in relation to the absolute power of God.”
    —René Descartes (1596–1650)

    “Skepticism is unbelief in cause and effect. A man does not see, that, as he eats, so he thinks: as he deals, so he is, and so he appears; he does not see that his son is the son of his thoughts and of his actions; that fortunes are not exceptions but fruits; that relation and connection are not somewhere and sometimes, but everywhere and always; no miscellany, no exemption, no anomaly,—but method, and an even web; and what comes out, that was put in.”
    —Ralph Waldo Emerson (1803–1882)

    “They who feel cannot keep their minds in the equilibrium of a pair of scales: fear and hope have no equiponderant weights.”
    —Horace Walpole (1717–1797)