Croatia
- Stjepan Andrijašević – Celta de Vigo, Rayo Vallecano – 1993-94, 1995–97
- Aljoša Asanović – Real Valladolid – 1995-96
- Marko Babić – Real Betis, Real Zaragoza – 2007-10
- Ivica Barbarić – Burgos CF – 1990-92
- Mate Bilić – Real Zaragoza, Sporting de Gijón – 2001-02, 2008–10
- Nenad Bjelica – Albacete, Real Betis – 1992-98
- Zvonimir Boban – Celta de Vigo – 2001-02
- Milivoj Bračun – Elche CF – 1988-89
- Igor Cvitanović – Real Sociedad – 1997-99
- Vlatko Đolonga – Alavés – 2000-01
- Ratomir Dujković – Real Oviedo – 1975-76
- Nenad Gračan – Real Oviedo – 1989-93
- Janko Janković – Real Valladolid, Real Oviedo, Hércules CF – 1988-95, 1996–97
- Robert Jarni – Real Betis, Real Madrid, UD Las Palmas – 1995-99, 2000–01
- Joško Jeličić – Sevilla FC – 1995-97
- Nikola Jerkan – Real Oviedo – 1990-96
- Goran Jurić – Celta de Vigo – 1992-93
- Ivan Jurić – Sevilla FC – 1999-00
- Siniša Končalović – RCD Mallorca – 1991-92
- Sergio Krešić – Burgos CF – 1976-78
- Ivan Leko – Málaga CF – 2001-05
- Danko Matrljan – CD Logroñés – 1987-88
- Goran Milanko – Cádiz CF – 1991-93
- Nenad Mirosavljević – Cádiz CF – 2005-06
- Luka Modrić - Real Madrid - 2012-13
- Ivica Mornar – Sevilla FC – 1996-97
- Dubravko Pavličić – Hércules CF, UD Salamanca – 1996-99
- Alen Peternac – Real Valladolid, Real Zaragoza – 1995-01
- Nenad Pralija – RCD Espanyol – 1996-99
- Robert Prosinečki – Real Madrid, Real Oviedo, FC Barcelona, Sevilla FC – 1991-97
- Ivan Rakitić – Sevilla FC, – 2011-
- Mauro Ravnić – Real Valladolid, UE Lleida – 1988-90, 1991–92, 1993–94
- Daniel Šarić – Sporting de Gijón – 1993-95
- Dragan Skočić – SD Compostela – 1994-96
- Mario Stanić – Sporting de Gijón – 1993-94
- Igor Štimac – Cádiz CF – 1992-93
- Davor Šuker – Sevilla FC, Real Madrid – 1991-99
- Ivica Šurjak – Real Zaragoza – 1984-85
- Zoran Varvodić – Cádiz CF – 1992-93
- Goran Vlaović – Valencia CF – 1996-00
- Goran Vučević – FC Barcelona, CP Mérida – 1992-93, 1995–96
- Jurica Vučko – Alavés – 2000-02
- Zoran Vulić – RCD Mallorca – 1989-91
Read more about this topic: List Of Foreign La Liga Players