Lacquer - Urushiol-based Lacquers

Urushiol-based Lacquers

Urushiol-based lacquers differ from most others, being slow-drying, water-based, and set by oxidation and polymerization, rather than by evaporation alone. In order for it to set properly it requires a humid and warm environment. The phenols oxidize and polymerize under the action of an enzyme laccase, yielding a substrate that, upon proper evaporation of its water content, is hard. These lacquers produce very hard, durable finishes that are both beautiful and very resistant to damage by water, acid, alkali or abrasion. The active ingredient of the resin is urushiol, a mixture of various phenols suspended in water, plus a few proteins. The resin is derived from a tree indigenous to China, species Toxicodendron vernicifluum, commonly known as the Lacquer Tree. Lacquer skills became very highly developed in Asia, and many highly decorated pieces were produced.

During the Shang Dynasty (ca. 1600–1046 BCE), the sophisticated techniques used in the lacquer process were first developed and it became a highly artistic craft, although various prehistoric lacquerwares have been unearthed in China dating back to the Neolithic period and objects with lacquer coating in Japan from the late Jōmon period. The earliest extant lacquer object, a red wooden bowl, was unearthed at a Hemudu culture (ca. 5000-4500 BCE) site in China. By the Han Dynasty (206 BCE – 220 CE), many centres of lacquer production became firmly established. The knowledge of the Chinese methods of the lacquer process spread from China during the Han, Tang and Song dynasties, eventually it was introduced to Korea, Japan, Southeast and South Asia.

The process of lacquer application in India is different from that which is followed in China and Japan. There are two types of lacquer: one obtained from the T. vernicifluum tree and the other from an insect. In India the insect lac was once used from which a red dye was first extracted, later what was left of the insect was a grease that was used for lacquering objects. The fresh resin from the T. vernicifluum trees causes urushiol-induced contact dermatitis and great care is required in its use. The Chinese treated the allergic reaction with shell-fish.

Trade of lacquer objects travelled through various routes to the Middle East. Known applications of lacquer in China included coffins, music instruments, furniture, and various household items. Lacquer mixed with powdered cinnabar is used to produce the traditional red lacquerware from China.

The trees must be at least 10 years old before cutting to bleed the resin. It sets by a process called "aqua-polymerization", absorbing oxygen to set; placing in a humid environment allows it to absorb more oxygen from the evaporation of the water.

Lacquer-yielding trees in Thailand, Vietnam, Burma and Taiwan, called Thitsi, are slightly different; they do not contain urushiol, but similar substances called "laccol" or "thitsiol". The end result is similar but softer than the Chinese or Japanese lacquer. Unlike Japanese and Chinese Toxicodendron verniciflua resin, Burmese lacquer does not cause allergic reactions; it sets slower, and is painted by craftsmen's hands without using brushes.

Raw lacquer can be "coloured" by the addition of small amounts of iron oxides, giving red or black depending on the oxide. There is some evidence that its use is even older than 8,000 years from archaeological digs in China. Later, pigments were added to make colours. It is used not only as a finish, but mixed with ground fired and unfired clays applied to a mould with layers of hemp cloth, it can produce objects without need for another core like wood. The process is called "kanshitsu" in Japan. Advanced decorative techniques using additional materials such as gold and silver powders and flakes ("makie") were refined to very high standards in Japan also after having been introduced from China. In the lacquering of the Chinese musical instrument, the guqin, the lacquer is mixed with deer horn powder (or ceramic powder) to give it more strength so it can stand up to the fingering.

There are more than four forms of urushiol which is written as thus:

R = (CH₂)₁₄CH₃ or
R = (CH₂)₇CH=CH(CH₂)₅CH₃ or
R = (CH₂)₇CH=CHCH₂CH=CH(CH₂)₂CH₃ or
R = (CH₂)₇CH=CHCH₂CH=CHCH=CHCH₃ or
R = (CH₂)₇CH=CHCH₂CH=CHCH₂CH=CH₂ and others.