Mineralogy
The pristine volcanic mineralogy of komatiites is composed of forsteritic olivine (Fo90 and upwards), calcic and often chromian pyroxene, anorthite (An85 an upwards) and chromite.
A considerable population of komatiite examples show a cumulate texture and morphology. The usual cumulate mineralogy is highly magnesium rich forsterite olivine, though chromian pyroxene cumulates are also possible (though rarer).
Volcanic rocks rich in magnesium may be produced by accumulation of olivine phenocrysts in basalt melts of normal chemistry: an example is picrite. Part of the evidence that komatiites are not magnesium-rich simply because of cumulate olivine is textural: some contain spinifex, a texture attributable to rapid crystallization of the olivine from a magnesium-rich melt.
Another line of evidence is that the MgO content of olivines formed in komatiites is toward the nearly pure MgO forsterite composition, which can only be achieved in bulk by crystallisation of olivine from a highly magnesian melt.
The often rarely preserved flow top breccia and pillow margin zones in some komatiite flows are essentially volcanic glass, quenched in contact with overlying water or air. Because they are quenched, they represent the liquid composition of the komatiites, and thus record an anhydrous MgO content of up to 32% MgO. Some of the highest magnesian komatiites with clear textural preservation are those of the Weltevreden Formation of the Barberton belt in South Africa, where liquids with up to 34% MgO can be inferred using bulk rock and olivine compositions.
The mineralogy of a komatiite varies systematically through the typical stratigraphic section of a komatiite flow and reflects magmatic processes which komatiites are susceptible to during their eruption and cooling. The typical mineralogical variation is from a flow base composed of olivine cumulate, to a spinifex textured zone composed of bladed olivine and ideally a pyroxene spinifex zone and olivine-rich chill zone on the upper eruptive rind of the flow unit. The "spinifex" texture is named after an Australian grass that grows in clumps with similar shapes.
Primary (magmatic) mineral species also encountered in komatiites include olivine, the pyroxenes augite, pigeonite and bronzite, plagioclase, chromite, ilmenite and rarely pargasitic amphibole. Secondary (metamorphic) minerals include serpentine, chlorite, amphibole, sodic plagioclase, quartz, iron oxides and rarely phlogopite, baddeleyite, and pyrope or hydrogrossular garnet.
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