Iridium(III) Chloride - Preparation

Preparation

Iridium is separated from the other platinum group metals as crystalline ammonium hexachloroiridate(IV), (NH4)2 (CAS number ), which can be reduced to iridium metal in a stream of hydrogen. The spongy Ir thus produced reacts with chlorine at 300–400 °C to produce iridium(III) chloride. Like the related rhodium compound, IrCl3 adopts the structure seen for aluminium chloride.

The hydrated form is obtained by heating hydrated iridium(III) oxide with hydrochloric acid.

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