Helium - Isotopes

Isotopes

There are eight known isotopes of helium, but only helium-3 and helium-4 are stable. In the Earth's atmosphere, there is one 3He atom for every million 4He atoms. Unlike most elements, helium's isotopic abundance varies greatly by origin, due to the different formation processes. The most common isotope, helium-4, is produced on Earth by alpha decay of heavier radioactive elements; the alpha particles that emerge are fully ionized helium-4 nuclei. Helium-4 is an unusually stable nucleus because its nucleons are arranged into complete shells. It was also formed in enormous quantities during Big Bang nucleosynthesis.

Helium-3 is present on Earth only in trace amounts; most of it since Earth's formation, though some falls to Earth trapped in cosmic dust. Trace amounts are also produced by the beta decay of tritium. Rocks from the Earth's crust have isotope ratios varying by as much as a factor of ten, and these ratios can be used to investigate the origin of rocks and the composition of the Earth's mantle. 3He is much more abundant in stars, as a product of nuclear fusion. Thus in the interstellar medium, the proportion of 3He to 4He is around 100 times higher than on Earth. Extraplanetary material, such as lunar and asteroid regolith, have trace amounts of helium-3 from being bombarded by solar winds. The Moon's surface contains helium-3 at concentrations on the order of 0.01 ppm, much higher than the ca. 5 ppt found in the Earth's atmosphere. A number of people, starting with Gerald Kulcinski in 1986, have proposed to explore the moon, mine lunar regolith and use the helium-3 for fusion.

Liquid helium-4 can be cooled to about 1 kelvin using evaporative cooling in a 1-K pot. Similar cooling of helium-3, which has a lower boiling point, can achieve about 0.2 kelvin in a helium-3 refrigerator. Equal mixtures of liquid 3He and 4He below 0.8 K separate into two immiscible phases due to their dissimilarity (they follow different quantum statistics: helium-4 atoms are bosons while helium-3 atoms are fermions). Dilution refrigerators use this immiscibility to achieve temperatures of a few millikelvins.

It is possible to produce exotic helium isotopes, which rapidly decay into other substances. The shortest-lived heavy helium isotope is helium-5 with a half-life of 7.6×10−22 s. Helium-6 decays by emitting a beta particle and has a half-life of 0.8 second. Helium-7 also emits a beta particle as well as a gamma ray. Helium-7 and helium-8 are created in certain nuclear reactions. Helium-6 and helium-8 are known to exhibit a nuclear halo.

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