Real Gas Relations
As temperature increases, higher energy rotational and vibrational states become accessible to molecular gases, thus increasing the number of degrees of freedom and lowering . For a real gas, both and increase with increasing temperature, while continuing to differ from each other by a fixed constant (as above, = ) which reflects the relatively constant P*V difference in work done during expansion, for constant pressure vs. constant volume conditions. Thus, the ratio of the two values, decreases with increasing temperature. For more information on mechanisms for storing heat in gases, see the gas section of specific heat capacity.
Read more about this topic: Heat Capacity Ratio
Famous quotes containing the words real, gas and/or relations:
“We are tainted by modern philosophy which has taught us that all is good, whereas evil has polluted everything and in a very real sense all is evil, since nothing is in its proper place.”
—Joseph De Maistre (1753–1821)
“one pale woman all alone,
The daylight kissing her wan hair,
Loitered beneath the gas lamps’ flare,
With lips of flame and heart of stone.”
—Oscar Wilde (1854–1900)
“Society does not consist of individuals but expresses the sum of interrelations, the relations within which these individuals stand.”
—Karl Marx (1818–1883)