Fluoride Volatility

Fluoride volatility is jargon that describes the volatility of fluorides, which is relevant to the separation of radionuclides. Hexafluorides and pentafluorides have much lower boiling points than the lower-valence fluorides. Most difluorides and trifluorides have high boiling points, while most tetrafluorides and monofluorides fall in between. The volatility of fluorides is the basis of technologies used in the processing and reprocessing of nuclear fuel, both of the conventional fuel rods used in today's LWRs and as a part of a molten salt reactor system.

Fluorides by boiling and melting points
Fluoride
Z
Boiling
°C
Melting
°C
Key halflife
Yield
SeF6 34 −46.6 −50.8 79Se:65ky .04%
TeF6 52 −39 −38 127mTe:109d
IF7 53 4.8 (1 atm) 6.5 (tripoint) 129I:15.7my 0.54%
MoF6 42 34 17.4 99Mo:2.75d
PuF6 94 52 (subl) 62 239Pu:24ky
TcF6 43 55.3 37.4 99Tc:213ky 6.1%
NpF6 93 55.18 54.4 237Np:2.14my
UF6 92 56.5 (subl) 64.8 233U:160ky
ReF7 75 73.72 48.3 Not FP
BrF5 35 40.25 −61.30 81Br:stable
IF5 53 97.85 9.43 129I:15.7my 0.54%
SbF5 51 141 8.3 125Sb:2.76y
RuOF4 44 184 115 106Ru:374d
RuF5 44 227 86.5 106Ru:374d
NbF5 41 234 79 95Nb:35d low
SnF4 50 705 750 (subl) 121m1Sn:44y
126Sn:230ky
0.013%
?
ZrF4 40 905 932 (tripoint) 93Zr:1.5my 6.35%
AgF 47 1159 435 109Ag:stable
CsF 55 1251 682 137Cs:30.2y
135Cs:2.3my
6.19%
6.54%
BeF2 4 1327 552
RbF 37 1410 795
UF4 92 1417 1036 233U:160ky
FLiBe 1430 459 stable
FLiNaK 1570 454 stable
LiF 3 1676 848 stable
ThF4 90 1680 1110
CdF2 48 1748 1110 113mCd:14.1y
YF3 39 2230 1150 91Y:58.51d
InF3 49 >1200 1170
BaF2 56 2260 1368 140Ba:12.75d
TbF3 65 2280 1172
GdF3 64 1231 159Gd:18.5h
PmF3 61 1338 147Pm:2.62y
EuF3 63 2280 1390 155Eu:4.76y
NdF3 60 2300 1374 147Nd:11d
PrF3 59 1395 143Pr:13.57d
CeF3 58 2327 1430 144Ce:285d
SmF3 62 2427 1306 151Sm:90y 0.419%
?
SrF2 38 2460 1477 90Sr: 29.1y 5.8%
LaF3 57 1493 140La:1.68d

Read more about Fluoride Volatility:  Reprocessing Methods, Volatility and Valence