Others
- Iolo Morganwg (real name Edward Williams, 1747–1826), Welsh antiquarian
- Edward Williams (engraver) (c.1755–1797?), English engraver
- Edward Williams (painter) (1781–1855), English painter
- Edward Leader Williams (1828–1910), English engineer
- Edward Christopher Williams (1871–1929), American librarian
- Edward Charles Williams (1807–1881), English landscape painter
- Edward Francis Williams (1903–1970), British newspaper editor
- Edward Williams (businessman) (1843–1903), American businessman who co-founded the Sherwin-Williams Company
- Edward Wyckoff Williams (born 1978), African-American author and political and economic analyst
- Ed Williams (actor), American actor
- Eddie Williams (saxophonist) (born 1910), American musician
- Edward Williams (minister) (1750–1813), Welsh nonconformist minister, theological writer, and tutor
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