Dye Laser - Operation

Operation

The dyes used in these lasers contain rather large organic molecules which fluoresce. The incoming light excites the dye molecules into the state of being ready to emit stimulated radiation, the singlet state. In this state, the molecules emit light via fluorescence, and the dye is transparent to the lasing wavelength. Within a microsecond, or less, the molecules will change to their triplet state. In the triplet state, light is emitted via phosphorescence, and the molecules absorb the lasing wavelength, making the dye opaque. Liquid dyes also have an extremely high lasing threshold. Flashlamp pumped lasers need a flash with an extremely short duration, to deliver the large amounts of energy necessary to bring the dye past threshold before triplet absorption overcomes singlet emission. Dye lasers with an external pump laser can direct enough energy of the proper wavelength into the dye with a relatively small amount of input energy, but the dye must be circulated at high speeds to keep the triplet molecules out of the beam path.

Since organic dyes tend to decompose under the influence of light, the dye solution is normally circulated from a large reservoir. The dye solution can be flowing through a cuvette, i.e., a glass container, or be as a dye jet, i.e., as a sheet-like stream in open air from a specially-shaped nozzle. With a dye jet, one avoids reflection losses from the glass surfaces and contamination of the walls of the cuvette. These advantages come at the cost of a more-complicated alignment.

Liquid dyes have very high gain as laser media. The beam only needs to make a few passes through the liquid to reach full design power, and hence, the high transmittance of the output coupler. The high gain also leads to high losses, because reflection from the dye cell walls, or flashlamp reflector, will dramatically reduce the amount of energy available to the beam. Pump cavities are often coated, anodized, or otherwise made of a material that will not reflect at the lasing wavelength while reflecting at the pump wavelength.