Common Ligands
Particularly common diphosphine ligands are shown in the table below:
Abbreviation | Common name (from which abbreviation derived) |
IUPAC Name (rarely used) |
---|---|---|
dppm | 1,1-Bis(diphenylphosphino)methane | Methylene bis(diphenylphosphane) |
dmpe | 1,2-Bis(dimethylphosphino)ethane | Ethane-1,2-diylbis(dimethylphosphane) |
dippe | 1,2-Bis(diisopropylphosphino)ethane | Ethane-1,2-diylbis(di(propan-2-yl)phosphane) |
dppe | 1,2-Bis(diphenylphosphino)ethane | Ethane-1,2-diylbis(diphenylphosphane) |
DIPAMP | Dimer of phenylanisylmethylphosphine | Ethane-1,2-diylbis |
dppp | 1,3-Bis(diphenylphosphino)propane | Propane-1,3-diylbis(diphenylphosphane) |
dppb | 1,4-Bis(diphenylphosphino)butane | Butane-1,4-diylbis(diphenylphosphane) |
Chiraphos | 2,3-Bis(diphenylphosphino)butane | Butane-2,3-diylbis(diphenylphosphane) |
BINAP | 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl | 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphane) |
Xantphos | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene | 9,9-Dimethyl-9H-xanthene-4,5-diylbis(diphenylphosphane) |
SPANphos | 4,4,4',4',6,6'-Hexamethyl-2,2'-spirobichromane-8,8'-diylbis(diphenylphosphane) | |
SEGPHOS | 4,4'-Bi-1,3-benzodioxole-5,5'-diylbis(diphenylphosphane) | |
dppf | 1,1'-Bis(diphenylphosphino)ferrocene | |
Me-DuPhos | 1,2-Bis(2,5-dimethylphospholano)benzene | 1,2-Phenylenebis(2,5-dimethylphospholane) |
Josiphos | (Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
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