Diphosphines - Common Ligands

Common Ligands

Particularly common diphosphine ligands are shown in the table below:

Abbreviation Common name
(from which abbreviation derived)
IUPAC Name (rarely used)
dppm 1,1-Bis(diphenylphosphino)methane Methylene bis(diphenylphosphane)
dmpe 1,2-Bis(dimethylphosphino)ethane Ethane-1,2-diylbis(dimethylphosphane)
dippe 1,2-Bis(diisopropylphosphino)ethane Ethane-1,2-diylbis(di(propan-2-yl)phosphane)
dppe 1,2-Bis(diphenylphosphino)ethane Ethane-1,2-diylbis(diphenylphosphane)
DIPAMP Dimer of phenylanisylmethylphosphine Ethane-1,2-diylbis
dppp 1,3-Bis(diphenylphosphino)propane Propane-1,3-diylbis(diphenylphosphane)
dppb 1,4-Bis(diphenylphosphino)butane Butane-1,4-diylbis(diphenylphosphane)
Chiraphos 2,3-Bis(diphenylphosphino)butane Butane-2,3-diylbis(diphenylphosphane)
BINAP 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphane)
Xantphos 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 9,9-Dimethyl-9H-xanthene-4,5-diylbis(diphenylphosphane)
SPANphos 4,4,4',4',6,6'-Hexamethyl-2,2'-spirobichromane-8,8'-diylbis(diphenylphosphane)
SEGPHOS 4,4'-Bi-1,3-benzodioxole-5,5'-diylbis(diphenylphosphane)
dppf 1,1'-Bis(diphenylphosphino)ferrocene
Me-DuPhos 1,2-Bis(2,5-dimethylphospholano)benzene 1,2-Phenylenebis(2,5-dimethylphospholane)
Josiphos (Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

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