Size-consistency and Size-extensivity Problem
Davidson correction improves both size consistency and size extensivity of CISD energies. Therefore, Davidson correction is frequently referred to in literature as size-consistency correction or size-extensivity correction.
However, neither Davidson correction itself nor the corrected energies are size-consistent or size-extensive. This is especially the case in larger molecules, where contribution from higher than quadruple excitations becomes more significant.
Read more about this topic: Davidson Correction
Famous quotes containing the word problem:
“The problem of the twentieth century is the problem of the color-linethe relation of the darker to the lighter races of men in Asia and Africa, in America and the islands of the sea. It was a phase of this problem that caused the Civil War.”
—W.E.B. (William Edward Burghardt)