Naming of Inorganic Compounds
IUPAC have introduced the polyhedral symbol as part of their IUPAC nomenclature of inorganic chemistry 2005 recommendations to describe the geometry around an atom in a compound.
IUCr have proposed a symbol which is shown as a superscript in square brackets in the chemical formula. For example CaF2 would be CaF2, where means cubic coordination and means tetrahedral. The equivalent symbols in IUPAC are CU−8 and T−4 respectively.
The IUPAC symbol is applicable to complexes and molecules whereas the IUCr proposal applies to crystalline solids.
Read more about this topic: Coordination Geometry
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