Conjugate Variables (thermodynamics) - The Chemical Potential/particle Number Pair

The Chemical Potential/particle Number Pair

The chemical potential is like a force which pushes an increase in particle number. In cases where there are a mixture of chemicals and phases, this is a useful concept. For example if a container holds water and water vapor, there will be a chemical potential (which is negative) for the liquid pushing water molecules into the vapor (evaporation) and a chemical potential for the vapor, pushing vapor molecules into the liquid (condensation). Only when these "forces" equilibrate is equilibrium obtained.

Read more about this topic:  Conjugate Variables (thermodynamics)

Famous quotes containing the words chemical, potential, particle, number and/or pair:

    If Thought is capable of being classed with Electricity, or Will with chemical affinity, as a mode of motion, it seems necessary to fall at once under the second law of thermodynamics as one of the energies which most easily degrades itself, and, if not carefully guarded, returns bodily to the cheaper form called Heat. Of all possible theories, this is likely to prove the most fatal to Professors of History.
    Henry Brooks Adams (1838–1918)

    Raising a daughter is an extremely political act in this culture. Mothers have been placed in a no-win situation with their daughters: if they teach their daughters simply how to get along in a world that has been shaped by men and male desires, then they betray their daughters’ potential But, if they do not, they leave their daughters adrift in a hostile world without survival strategies.
    Elizabeth Debold (20th century)

    You don’t hold any mystery for me, darling, do you mind? There isn’t a particle of you that I don’t know, remember, and want.
    Noël Coward (1899–1973)

    In view of the fact that the number of people living too long has risen catastrophically and still continues to rise.... Question: Must we live as long as modern medicine enables us to?... We control our entry into life, it is time we began to control our exit.
    Max Frisch (1911–1991)

    I saw a guide-post surmounted by a pair of moose horns.... They are sometimes used for ornamental hat-trees, together with deer’s horns, in front entries; but ... I trust that I shall have a better excuse for killing a moose than that I may hang my hat on his horns.
    Henry David Thoreau (1817–1862)