Chloroplatinic Acid - Reactions

Reactions

When hexachloroplatinic acid is heated, it decomposes through platinum(IV) chloride and platinum(II) chloride to elemental platinum, although the reactions do not occur stepwise, cleanly:

(H3O)2PtCl6ยทn H2O PtCl4 + 2 HCl + (n + 2) H2O
PtCl4 PtCl2 + Cl2
PtCl2 Pt + Cl2

All three reactions are reversible.

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