Organic and Main Group Chemistry
In the presence of strong acids and water, carbon monoxide reacts with alkenes to form carboxylic acids in a process known as the Koch–Haaf reaction. In the Gattermann-Koch reaction, arenes are converted to benzaldehyde derivatives in the presence of AlCl3 and HCl. Organolithium compounds (e.g. butyl lithium) react with carbon monoxide, but these reactions have little scientific use.
Although CO reacts with carbocations and carbanions, it is relatively nonreactive toward organic compounds without the intervention of metal catalysts.
With main group reagents, CO undergoes several noteworthy reactions. Chlorination of CO is the industrial route to the important compound phosgene. With borane CO forms an adduct, H3BCO, which is isoelectronic with the acylium cation +. CO reacts with sodium to give products resulting from C-C coupling such as sodium acetylenediolate 2Na+·C2O2−
2. It reacts with molten potassium to give a mixture of an organometallic compound, potassium acetylenediolate 2K+·C2O2−
2, potassium benzenehexolate 6K+ C6O6−
6, and potassium rhodizonate 2K+·C6O2−
6.
The compounds cyclohexanehexone or triquinoyl (C6O6) and cyclopentanepentone or leuconic acid (C5O5), which so far have been obtained only in trace amounts, can be regarded as polymers of carbon monoxide.
At pressures of over 5 gigapascals, carbon monoxide disproportionates into carbon dioxide (CO2) and a solid polymer of carbon and oxygen, in 3:2 atomic ratio.
Read more about this topic: Carbon Monoxide
Famous quotes containing the words organic, main, group and/or chemistry:
“Technology represents intelligence systematically applied to the problem of the body. It functions to amplify and surpass the organic limits of the body; it compensates for the body’s fragility and vulnerability ...”
—Shoshana Zuboff (b. 1951)
“The main thing is that everything become simple, easy enough for a child to understand; that each act be ordered, that good and evil be decided arbitrarily, thus clearly.”
—Albert Camus (1913–1960)
“For me, as a beginning novelist, all other living writers form a control group for whom the world is a placebo.”
—Nicholson Baker (b. 1957)
“Science with its retorts would have put me to sleep; it was the opportunity to be ignorant that I improved. It suggested to me that there was something to be seen if one had eyes. It made a believer of me more than before. I believed that the woods were not tenantless, but choke-full of honest spirits as good as myself any day,—not an empty chamber, in which chemistry was left to work alone, but an inhabited house,—and for a few moments I enjoyed fellowship with them.”
—Henry David Thoreau (1817–1862)