Types of Substitutes
Hodgdon's Pyrodex was the first widely available substitute on the market. Pyrodex is less sensitive to ignition than black powder, and uses the same shipping and storage guidelines as smokeless powder. Pyrodex is more energetic per unit of mass than black powder, but it is less dense, and can be substituted at a 1:1 ratio by volume for black powder in many applications. Pyrodex is similar in composition to black powder, consisting primarily of charcoal, sulfur, and potassium nitrate, but it also contains graphite and potassium perchlorate, plus additional ingredients protected by trade secret. Originally available as loose powder in two granularities, RS (Rifle/Shotgun) equal to FFG blackpowder, and P (Pistol) equal to FFFg black powder, Pyrodex is now becoming available in Select and solid pellet varieties. While Pyrodex offers improved safety and increased efficiency (in terms of shots per pound of powder) over black powder, the level of fouling is similar; Pyrodex is caustic and corrosive.
Hodgdon also makes Triple Seven, one of the family of sulfurless black powder substitutes. Triple Seven and Black Mag3 are more energetic than black powder, and produce higher velocities and pressures. Still burning carbon, the carbon-based fuel burned here is from the sugar family, not from charcoal.
Western Powders Company introduced Blackhorn 209 in 2008. Like many other black powder substitutes, it is made to be a volumetric substitute of black powder. It is dispensed in "black powder powder measures" for muzzleloading applications. Blackhorn 209 is essentially non-corrosive, low-fouling, very consistent in gas generation, but non-hygroscopic.
Read more about this topic: Black Powder Substitute
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