Kinetic Theory's Interpretation of Arrhenius Equation
Arrhenius argued that for reactants to transform into products, they must first acquire a minimum amount of energy, called the activation energy Ea. At an absolute temperature T, the fraction of molecules that have a kinetic energy greater than Ea can be calculated from statistical mechanics. The concept of activation energy explains the exponential nature of the relationship, and in one way or another, it is present in all kinetic theories.
The calculations for reaction rate constants involve an energy averaging over a Maxwell-Boltzmann distribution with as lower bound and so are often of the type of incomplete gamma functions, which turn out to be proportional to .
Read more about this topic: Arrhenius Equation
Famous quotes containing the words kinetic, theory and/or equation:
“The poem has a social effect of some kind whether or not the poet wills it to have. It has kinetic force, it sets in motion ... [ellipsis in source] elements in the reader that would otherwise be stagnant.”
—Denise Levertov (b. 1923)
“... the first reason for psychology’s failure to understand what people are and how they act, is that clinicians and psychiatrists, who are generally the theoreticians on these matters, have essentially made up myths without any evidence to support them; the second reason for psychology’s failure is that personality theory has looked for inner traits when it should have been looking for social context.”
—Naomi Weisstein (b. 1939)
“Jail sentences have many functions, but one is surely to send a message about what our society abhors and what it values. This week, the equation was twofold: female infidelity twice as bad as male abuse, the life of a woman half as valuable as that of a man. The killing of the woman taken in adultery has a long history and survives today in many cultures. One of those is our own.”
—Anna Quindlen (b. 1952)