AP 42 Compilation of Air Pollutant Emission Factors - Chapters in AP 42, Volume I, Fifth Edition

Chapters in AP 42, Volume I, Fifth Edition

Chapter 1 External Combustion Sources
Chapter 2 Solid Waste Disposal
Chapter 3 Stationary Internal Combustion Sources
Chapter 4 Evaporation Loss Sources
Chapter 5 Petroleum Industry
Chapter 6 Organic Chemical Process Industry
Chapter 7 Liquid Storage Tanks
Chapter 8 Inorganic Chemical Industry
Chapter 9 Food and Agricultural Industries
Chapter 10 Wood Products Industry
Chapter 11 Mineral Products Industry
Chapter 12 Metallurgical Industry
Chapter 13 Miscellaneous Sources
Chapter 14 Greenhouse Gas Biogenic Sources
Chapter 15 Ordnance Detonation
Appendix A Miscellaneous Data & Conversion Factors
Appendix B.1
Particle Size Distribution Data and Sized Emission Factors
for Selected Sources
Appendix B.2 Generalized Particle Size Distributions
Appendix C.1 Procedures for Sampling Surface/Bulk Dust Loading
Appendix C.2
Procedures for Laboratory Analysis of Surface/Bulk Dust
Loading Samples

Chapter 5, Section 5.1 "Petroleum Refining" discusses the air pollutant emissions from the equipment in the various refinery processing units as well as from the auxiliary steam-generating boilers, furnaces and engines, and Table 5.1.1 includes the pertinent emission factors. Table 5.1.2 includes the emission factors for the fugitive air pollutant emissions from the large wet cooling towers in refineries and from the oil/water separators used in treating refinery wastewater.

The fugitive air pollutant emission factors from relief valves, piping valves, open-ended piping lines or drains, piping flanges, sample connections, and seals on pump and compressor shafts are discussed and included the report EPA-458/R-95-017, "Protocol for Equipment Leak Emission Estimates" which is included in the Chapter 5 section of AP 42. That report includes the emission factors developed by the EPA for petroleum refineries and for the synthetic organic chemical industry (SOCMI).

In most cases, the emission factors in Chapter 5 are included for both uncontrolled conditions before emission reduction controls are implemented and controlled conditions after specified emission reduction methods are implemented.

Chapter 7 "Liquid Storage Tanks" is devoted to the methodology for calculating the emissions losses from the six basic tank designs used for organic liquid storage: fixed roof (vertical and horizontal), external floating roof, domed external (or covered) floating roof, internal floating roof, variable vapor space, and pressure (low and high). The methodology in Chapter 7 was developed by the American Petroleum Institute in collaboration with the EPA.

The EPA has developed a software program named "TANKS" which performs the Chapter 7 methodology for calculating emission losses from storage tanks. The program's installer file along with a user manual, and the source code are available on the Internet.

Chapters 5 and 7 discussed above are illustrative of the type of information contained in the other chapters of AP 42. It should also be noted that many of the fugitive emission factors in Chapter 5 and the emissions calculation methodology in Chapter 7 and the TANKS program also apply to many other industrial categories besides the petroleum industry.

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