Anionic Addition Polymerization - Propagation

Propagation

Propagation in anionic addition polymerization results in the complete consumption of monomer. It is very fast and occurs at low temperatures. This is due to the anion not being very stable, the speed of the reaction as well as that heat is released during the reaction. The stability can be greatly enhanced by reducing the temperatures to near 0˚C. The propagation rates are generally fairly high compared to the decay reaction, so the overall polymerization rates is generally not affected.

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