Anionic addition polymerization is a form of chain-growth polymerization or addition polymerization that involves the polymerization of vinyl monomers with strong electronegative groups. This polymerization is carried out through a carbanion active species. Like all addition polymerizations, it takes place in three steps: chain initiation, chain propagation, and chain termination. Living polymerizations, which lack a formal termination pathway, occur in many anionic addition polymerizations. The advantage of living anionic addition polymerizations is that they allow for the control of structure and composition.
Anionic polymerizations are used in the production of polydiene synthetic rubbers, solution styrene/butadiene rubbers (SBR), and styrenic thermoplastic elastomers.
Read more about Anionic Addition Polymerization: History, Monomer Characteristics, Solvent, Initiation, Propagation, Termination, Living Anionic Polymerization, Kinetics
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