Ammonium Bicarbonate - Reactions

Reactions

It dissolves in water to give a mildly alkaline solution. It is insoluble in acetone and alcohols.

Ammonium bicarbonate decomposes above about 36 °C into ammonia, carbon dioxide, and water in an endothermic process and so causes a drop in the temperature of the water:

NH4HCO3 → NH3 + H2O + CO2.

When treated with acids, carbon dioxide is also produced:

NH4HCO3 + HCl → NH4Cl + CO2 + H2O.

Reaction with base produces ammonia.

It reacts with sulfates of alkaline-earth metals to precipitating their carbonates:

CaSO4 + 2 NH4HCO3 → CaCO3 + (NH4)2SO4 + CO2 + H2O.

It also reacts with alkali metal halides, giving alkali metal bicarbonate and ammonium halide:

NH4HCO3 + NaCl → NH4Cl + NaHCO3;
NH4HCO3 + KI → NH4I + KHCO3;
NH4HCO3 + NaBr → NH4Br + NaHCO3.

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