Zirconium - Characteristics

Characteristics

Zirconium is a lustrous, greyish-white, soft, ductile and malleable metal which is solid at room temperature, though it becomes hard and brittle at lower purities. In powder form, zirconium is highly flammable, but the solid form is far less prone to ignition. Zirconium is highly resistant to corrosion by alkalis, acids, salt water and other agents. However, it will dissolve in hydrochloric and sulfuric acid, especially when fluorine is present. Alloys with zinc become magnetic below 35 K.

Zirconium's melting point is 1855 °C (3371 °F), and its boiling point is 4371 °C (7900 °F). Zirconium has an electronegativity of 1.33 on the Pauling scale. Of the elements within d-block, zirconium has the fourth lowest electronegativity after yttrium, lutetium and hafnium.

At room temperature zirconium exhibits a hexagonally close packed crystal structure, α-Zr, which changes to β-Zr a body-centered cubic crystal structure at 863 °C. Zirconium exists in the β-phase until the melting point.

ZrZn2 is one of only two substances to exhibit superconductivity and ferromagnetism simultaneously, with the other being UGe2.

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