Metallurgy
Most solids used are engineering materials consisting of crystalline solids in which the atoms or ions are arranged in a repetitive geometric pattern which is known as a lattice structure. The only exception is material that is made from glass which is a combination of a supercooled liquid and polymers which are aggregates of large organic molecules.
Crystalline solids cohesion is obtained by a metallic or chemical bond which is formed between the constituent atoms. Chemical bonds can be grouped into two types consisting of ionic and covalent. To form an ionic bond, either a valence or bonding electron separates from one atom and becomes attached to another atom to form oppositely charged ions. The bonding in the static position is when the ions occupy an equilibrium position where the resulting force between them is zero. When the ions are exerted in tension force, the inter-ionic spacing increases creating an electrostatic attractive force, while a repulsing force under compressive force between the atomic nuclei is dominant.
Covalent bonding is when the constituent atoms lose an electron(s) to form a cluster of ions, resulting in an electron cloud that is shared by the molecule as a whole. In both ionic and covalent boding the location of the ions and electrons are constrained relative to each other, thereby resulting in the bond being characteristically brittle.
Metallic bonding can be classified as a type of covalent bonding for which the constituent atoms of the same type and do not combine with one another to form a chemical bond. Atoms will lose an electron(s) forming an array of positive ions. These electrons are shared by the lattice which makes the electron cluster mobile, as the electrons are free to move as well as the ions. For this, it gives metals their relatively high thermal and electrical conductivity as well as being characteristically ductile.
Three of the most commonly used crystal lattice structures in metals are the body-centred cubic, face-centred cubic and close-packed hexagonal. Ferritic steel has a body-centred cubic structure and austenitic steel, non-ferrous metals like aluminium, copper and nickel have the face-centred cubic structure.
Ductility is an important factor in ensuring the integrity of structures by enabling them to sustain local stress concentrations without fracture. In addition, structures are required to be of an acceptable strength, which is related to a material's yield strength. In general, as the yield strength of a material increases, there is a corresponding reduction in fracture toughness.
A reduction in fracture toughness may also be attributed to the embitterment effect of impurities, or for body-centred cubic metals, from a reduction in temperature. Metals and in particular steels have a transitional temperature range where above this range the metal has acceptable notch-ductility while below this range the material becomes brittle. Within the range, the materials behavior is unpredictable. The reduction in fracture toughness is accompanied by a change in the fracture appearance. When above the transition, the fracture is primarily due to micro-void coalescence, which results in the fracture appearing fibrous. When the temperatures falls the fracture will show signs of cleavage facets. These two appearances are visible by the naked eye. Brittle fracture in steel plates may appear as chevron markings under the microscope. These arrow-like ridges on the crack surface point towards the origin of the fracture.
Fracture toughness is measured using a notched and pre-cracked rectangular specimen, of which the dimensions are specified in standards, for example ASTM E23. There are other means of estimating or measuring fracture toughness by the following: The Charpy impact test per ASTM A370; The crack-tip opening displacement (CTOD) test per BS 7448-1; The J integral test per ASTM E1820; The Pellini drop-weight test per ASTM E208.
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