Scientific Conclusions
Organic compounds seem to be common, for example, on asteroids, meteorites, comets and the icy bodies orbiting the Sun, so detecting no trace of any organic compound on the surface of Mars came as a surprise. The GC-MS was definitely working, because the controls were effective and it was able to detect traces of the cleaning solvents that had been used to sterilize it prior to launch. At the time, the total absence of organic material on the surface made the results of the biology experiments moot, since metabolism involving organic compounds were what those experiments were designed to detect. However, the general scientific community surmise that the Viking's biological tests remain inconclusive. Most researchers surmise that the results of the Viking biology experiments can be explained by purely chemical processes that do not require the presence of life, and the GC-MS results rule out life.
Despite the positive result from the Labeled Release experiment, a general assessment is that the results seen in the four experiments are best explained by oxidative chemical reactions with the Martian soil. One of the current conclusions is that the Martian soil, being continuously exposed to UV light from the Sun (Mars has no protective ozone layer), has built up a thin layer of a very strong oxidant. A sufficiently strong oxidizing molecule would react with the added water to produce oxygen and hydrogen, and with the nutrients to produce carbon dioxide (CO2).
On August 2008, the Phoenix lander detected perchlorate, a strong oxidizer when heated above 200°C. This was initially thought to be the cause of a false positive LR result. However, results of experiments published in December 2010 propose that organic compounds "could have been present" in the soil analyzed by both Viking 1 and 2, since NASA's Phoenix lander in 2008 detected perchlorate, which can break down organic compounds. The study's authors found that perchlorate can destroy organics when heated and produce chloromethane and dichloromethane as byproduct, the identical chlorine compounds discovered by both Viking landers when they performed the same tests on Mars. Because perchlorate would have broken down any Martian organics, the question of whether or not Viking found organic compounds is still wide open.
Read more about this topic: Viking Spacecraft Biological Experiments
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