A thermodynamic potential is a scalar function used to represent the thermodynamic state of a system. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term fundamental functions. One main thermodynamic potential that has a physical interpretation is the internal energy, U. It is the energy of configuration of a given system of conservative forces (that is why it is a potential) and only has meaning with respect to a defined set of references (or data). Expressions for all other thermodynamic energy potentials are derivable via Legendre transforms from an expression for U. In thermodynamics, certain forces, such as gravity, are typically disregarded when formulating expressions for potentials. For example, while all the working fluid in a steam engine may have higher energy due to gravity while sitting on top of Mt. Everest than it would at the bottom of the Mariana trench, the gravitational potential energy term in the formula for the internal energy would usually be ignored because changes in gravitational potential within the engine during operation would be negligible.
| Thermodynamics |
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| The classical Carnot heat engine |
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Branches
Classical · Statistical · Chemical Equilibrium / Non-equilibrium |
| Laws Zeroth · First · Second · Third |
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Systems
State: Equation of state Ideal gas · Real gas Phase of matter · Equilibrium Control volume · Instruments Read more about Thermodynamic Potential: Description and Interpretation, Natural Variables, The Fundamental Equations, The Equations of State, The Maxwell Relations, Euler Integrals, The Gibbs–Duhem Relation, Chemical Reactions Famous quotes containing the word potential:“Laughing at someone else is an excellent way of learning how to laugh at oneself; and questioning what seem to be the absurd beliefs of another group is a good way of recognizing the potential absurdity of many of one’s own cherished beliefs.” |