Change of Internal State of An Isolated System
If an isolated system is left long enough, it will reach a state of thermal equilibrium, in which its temperature will be uniform throughout, but not necessarily a state of thermodynamic equilibrium, if there is some structural barrier that can prevent some possible processes in the system from reaching equilibrium. An isolated system can change its temperature or its spatial distribution of temperature by changing the state of Longley, R.G. Van Name, Longmans, Green & Co., New York, 1928, volume 1, pages 55-353, particularly pages 144-150. A system prepared as a mixture of petrol vapour and air can be ignited by a spark and produce carbon dioxide and water; if this happens in an isolated system, it will increase the temperature of the system, and during the increase, the system is not in thermal equilibrium; but eventually the system will settle to a uniform temperature. In a system prepared as a block of ice floating in a bath of hot water, and then isolated, the ice can melt; during the melting, the system is not in thermal equilibrium; but eventually its temperature will become uniform. Such changes in isolated systems are irreversible in the sense that while such a change will occur spontanteously whenever the system is prepared in the same way, the reverse change will never occur spontanteously within the isolated system; this is a large part of the content of the second law of thermodynamics. Truly isolated systems hardly occur in nature, and nearly always are artificially prepared.
Read more about this topic: Thermal Equilibrium
Famous quotes containing the words change, internal, state, isolated and/or system:
“If we confine ourselves to one life role, no matter how pleasant it seems at first, we starve emotionally and psychologically. We need a change and balance in our daily lives. We need sometimes to dress up and sometimes to lie around in torn jeans. . . . Even a grimy factory can afford some relief from a grimy kitchen and vice versa.”
—Faye J. Crosby (20th century)
“Well designed, fully functional infant. Provides someone to live for as well as another mouth to feed. Produces cooing, gurgling and other adorable sounds. May cause similar behavior in nearby adults. Cries when hungry, sleepy or just because. Hand Wash with warm water and mild soap, then pat dry with soft cloth and talc. Internal mechanisms are self-cleaning... Two Genders: Male. Female. Five Colors: White. Black. Yellow. Red. Camouflage.”
—Alfred Gingold, U.S. humorist. Items From Our Catalogue, “Baby,” Avon Books (1982)
“The State never intentionally confronts a man’s sense, intellectual or moral, but only his body, his senses. It is not armed with superior wit or honesty, but with superior physical strength.”
—Henry David Thoreau (1817–1862)
“Literature is not exhaustible, for the sufficient and simple reason that a single book is not. A book is not an isolated entity: it is a narration, an axis of innumerable narrations. One literature differs from another, either before or after it, not so much because of the text as for the manner in which it is read.”
—Jorge Luis Borges (1899–1986)
“... the yearly expenses of the existing religious system ... exceed in these United States twenty millions of dollars. Twenty millions! For teaching what? Things unseen and causes unknown!... Twenty millions would more than suffice to make us wise; and alas! do they not more than suffice to make us foolish?”
—Frances Wright (1795–1852)