Vegetable Tanning
Vegetable tanning uses tannin (this is the origin of the name of the process). The tannins (a class of polyphenol astringent chemical) occur naturally in the bark and leaves of many plants. Tannins bind to the collagen proteins in the hide and coat them causing them to become less water-soluble, and more resistant to bacterial attack. The process also causes the hide to become more flexible. The primary barks, processed in Bark mills and used in modern times are chestnut, oak, redoul, tanoak, hemlock, quebracho, mangrove, wattle (acacia; see catechu), and myrobalan. Hides are stretched on frames and immersed for several weeks in vats of increasing concentrations of tannin. Vegetable tanned hide is flexible and is used for luggage and furniture.
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