Superalloy - Chemical Development

Chemical Development

Creep resistance is dependent on slowing the speed of dislocations within the crystal structure. In Ni-base superalloys the gamma prime phase present acts as a coherent barrier to dislocation motion and is a precipitate strengthener. Chemical additions such as aluminum and titanium promote the creation of the gamma prime phase. The gamma prime phase size can be precisely controlled by careful precipitation hardening heat treatments. Many superalloys are produced using a two-phase heat treatment that creates a dispersion of square gamma prime particles known as the primary phase, with a fine dispersion between these known as secondary gamma prime. Many other elements, both common and exotic, (including not only metals, but also metalloids and nonmetals) can be present; chromium, cobalt, molybdenum, tungsten, tantalum, aluminium, titanium, zirconium, niobium, rhenium, carbon, boron or hafnium are just a few examples. Cobalt base superalloys do not have a strengthening secondary phase like gamma prime.

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