Sulfur Monoxide - Production and Reactions

Production and Reactions

Production of SO as a reagent in organic syntheses has centred on using compounds that "extrude" SO. Examples include the decomposition of the relatively simple molecule thiirane 1-oxide: as well as more complex examples, such as a trisulfide oxide, C10H6S3O,

C2H4OS → C2H4 + SO

The SO molecule is thermodynamically unstable, converting initially to S2O2. SO inserts into alkenes, alkynes and dienes producing molecules with three membered rings containing sulfur.

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