Origins
Natural sulfur aerosols are formed in vast quantities from the SO2 ejected by volcanoes, which may be injected directly into the stratosphere during very large (Volcanic Explosivity Index, VEI, of 4 or greater) eruptions. A comprehensive analysis, dealing largely with tropospheric sulfur compounds in the atmosphere, is provided by Bates et al.
The IPCC AR4 says explosive volcanic events are episodic, but the stratospheric aerosols resulting from them yield substantial transitory perturbations to the radiative energy balance of the planet, with both shortwave and longwave effects sensitive to the microphysical characteristics of the aerosols.
As of 2009 there have been no explosive and climatically significant volcanic events since Mt. Pinatubo and consequently stratospheric aerosol concentrations are at the lowest concentrations since the satellite era and global coverage began in about 1980.
During periods lacking volcanic activity (and thus direct injection of SO2 into the stratosphere), oxidation of COS (carbonyl sulfide) dominates the production of stratospheric sulfur aerosol.
Read more about this topic: Stratospheric Sulfur Aerosols
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