In quantum chemistry, Slater's rules provide numerical values for the effective nuclear charge concept. In a many-electron atom, each electron is said to experience less than the actual nuclear charge owing to shielding or screening by the other electrons. For each electron in an atom, Slater's rules provide a value for the screening constant, denoted by s, S, or σ, which relates the effective and actual nuclear charges as
The rules were devised semi-empirically by John C. Slater and published in 1930.
Revised values of screening constants based on computations of atomic structure by the Hartree-Fock method were obtained by Enrico Clementi et al in the 1960s.
Read more about Slater's Rules: Rules, Example, Motivation
Famous quotes containing the word rules:
“The average educated man in America has about as much knowledge of what a political idea is as he has of the principles of counterpoint. Each is a thing used in politics or music which those fellows who practise politics or music manipulate somehow. Show him one and he will deny that it is politics at all. It must be corrupt or he will not recognize it. He has only seen dried figs. He has only thought dried thoughts. A live thought or a real idea is against the rules of his mind.”
—John Jay Chapman (1862–1933)