Silicon Tetrabromide - Synthesis

Synthesis

Silicon tetrabromide is synthesized by the reaction of silicon with hydrogen bromide at 600 °C.

Si + 4 HBr → SiBr4 + 2 H2

Side products include dibromosilane (SiH2Br2) and tribromosilane (SiHBr3).

Si + 2 HBr → SiH2Br2
Si + 3 HBr → SiHBr3 + H2

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