Silicon Monoxide - Solid (polymeric) SiO

Solid (polymeric) SiO

Potter reported SiO solid as yellowish-brown in color and as being an electrical and thermal insulator. The solid burns in oxygen and decomposes water with the liberation of hydrogen. It dissolves in warm alkali hydroxides and in hydrofluoric acid. Although Potter reported the heat of combustion of SiO to be 200 to 800 calories higher than that of an equilibrium mixture of Si and SiO2 (which could, arguably, be used as evidence that SiO is a unique chemical compound), recent microscopy and spectroscopy studies suggest that amorphous solid SiO is best considered as an inhomogeneous mixture of amorphous SiO2 and amorphous Si with some chemical bonding at the interface of the Si and SiO2 phases.

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