Classical Simulation
A simple 1/r potential results in a closed Keplerian elliptical orbit. In the presence of an external electric field Rydberg atoms can obtain very large electric dipole moments making them extremely susceptible to perturbation by the field. Figure 6 shows how application of an external electric field (known in atomic physics as a Stark field) changes the geometry of the potential, dramatically changing the behaviour of the electron. A Coulombic potential does not apply any torque as the force is always antiparallel to the position vector (always pointing along a line running between the electron and the nucleus):
- ,
- .
With the application of a static electric field, the electron feels a continuously changing torque. The resulting trajectory becomes progressively more distorted over time, eventually going through the full range of angular momentum from L = LMAX, to a straight line L=0, to the initial orbit in the opposite sense L = -LMAX.
The time period of the oscillation in angular momentum (the time to complete the trajectory in figure 7), almost exactly matches the quantum mechanically predicted period for the wavefunction to return to its initial state, demonstrating the classical nature of the Rydberg atom.
Read more about this topic: Rydberg Atom
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