Ruthenium(III) Chloride - Coordination Chemistry

Coordination Chemistry

As the most commonly available ruthenium compound, RuCl3·xH2O is the precursor to many hundreds of chemical compounds. The noteworthy property of ruthenium complexes, chlorides and otherwise, is the existence of more than one oxidation state, several of are kinetically inert. All second and third-row transition metals form exclusively low spin complexes, whereas ruthenium is special in the stability of adjacent oxidation states, especially Ru(II), Ru(III) (as in the parent RuCl3·xH2O) and Ru(IV).

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