Ordinaries
- Francisco Marvéz † (25 Oct 1897 - 17 Dec 1904)
- Arturo Celestino Álvarez † (16 Aug 1910 - 18 Dec 1919) Appointed, Coadjutor Bishop of Calabozo
- Marcos Sergio Godoy † (8 Mar 1920 - 21 Oct 1957)
- José Rafael Pulido Méndez † (21 Jun 1958 - 16 Jan 1961) Appointed, Coadjutor Archbishop of Mérida
- Domingo Roa Pérez † (16 Jan 1961 - 23 Dec 1992)
- Ramón Ovidio Pérez Morales (23 Dec 1992 - 5 Jun 1999)
- Ubaldo Ramón Santana Sequera, F.M.I. (11 Nov 2000 - present)
Read more about this topic: Roman Catholic Archdiocese Of Maracaibo