Ring Opening Metathesis Polymerisation - Industrial Applications

Industrial Applications

Ring-opening metathesis polymerization of cycloalkenes can produce many important petrochemicals; this is of particular importance in an industrial capacity because synthetic capabilities include linear polymers from inexpensive monomers or polymers with special properties, thus compensating for an additional expense. Some examples of polymers produced on an industrial level through ROMP catalysis are Vestenamer or trans-polyoctenamer which is the metathetical polymer of cyclooctene; Norsorex or polynorbornene is another important ROMP product on the market; Telene and Metton are polydicyclopentadiene products produced in a side reaction of the polymerization of norbornene.

The ROMP process is quite useful because a regular polymer with a regular amount of double bonds is formed. The resulting product can be subjected to partial or total hydrogenation or can be functionalized into more complex compounds.

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