In the history of science, the principle of maximum work was a postulate concerning the relationship between chemical reactions, heat evolution, and the potential work produced there from. The principle was developed in approximate form in 1875 by French chemist Marcellin Berthelot, in the field of thermochemistry, and then later in 1876 by American mathematical physicist Willard Gibbs, in the field of thermodynamics, in a more accurate form. Berthelot's version was essentially: "every pure chemical reaction is accompanied by evolution of heat." (and that this yields the maximum amount of work). The effects of irreversibility, however, showed this version to be incorrect. This was rectified, in thermodynamics, by incorporating the concept of entropy.
Read more about Principle Of Maximum Work: Overview, Thermochemistry, Thermodynamics, See Also
Famous quotes containing the words principle of, principle, maximum and/or work:
“I sincerely believe ... that banking establishments are more dangerous than standing armies, and that the principle of spending money to be paid by posterity, under the name of funding, is but swindling futurity on a large scale.”
—Thomas Jefferson (1743–1826)
“No habit or quality is more easily acquired than hypocrisy, nor any thing sooner learned than to deny the sentiments of our hearts and the principle we act from: but the seeds of every passion are innate to us, and nobody comes into the world without them.”
—Bernard Mandeville (1670–1733)
“Only at his maximum does an individual surpass all his derivative elements, and become purely himself. And most people never get there. In his own pure individuality a man surpasses his father and mother, and is utterly unknown to them.”
—D.H. (David Herbert)
“Auld Nature swears, the lovely Dears
Her noblest work she classes, O:
Her prentice han’ she try’d on man,
An’ then she made the lasses, O.”
—Robert Burns (1759–1796)