Potassium Superoxide - Structural Trends in Dioxygen Compounds

Structural Trends in Dioxygen Compounds

The derivatives of dioxygen, O2, have characteristic O-O distances that correlate with the bond order of the O-O bond.

Dioxygen compound name O-O distance in Å O-O bond order
O+
2
dioxygenyl cation 1.12 2.5
O2 dioxygen 1.21 2
O−
2
superoxide 1.28 1.5
O2−
2
peroxide 1.49 1

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